SIST EN 17322:2020
(Main)Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-ECD)
Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-ECD)
This European Standard specifies a method for quantitative determination of seven selected polychlorinated biphenyls (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 and PCB180) in soil, sludge, sediment, treated biowaste and waste and using GC-MS and GC-ECD.
The limit of detection depends on the determinants, the equipment used, the quality of chemicals used for the extraction of the sample and the clean-up of the extract.
Under the conditions specified in this European Standard, lower limit of application from 1 μg/kg (expressed as dry matter) for soils, sludge and biowaste to 10 μg/kg (expressed as dry matter) for solid waste can be achieved. For some specific samples the limit of 10 μg/kg cannot be reached.
Sludge, waste and treated biowaste may differ in properties, as well as in the expected contamination levels of PCBs and presence of interfering substances. These differences make it impossible to describe one general procedure. This European Standard contains decision tables based on the properties of the sample and the extraction and clean-up procedure to be used.
NOTE For the analysis of PCB in insulating liquids, petroleum products, used oils and aqueous samples is referred to EN 61619, EN 12766–1 and EN ISO 6468 respectively.
The method may be applied to the analysis of other PCB congeners not specified in the scope, provided suitability is proven by proper in-house validation experiments
Feststoffe in der Umwelt - Bestimmung von polychlorierten Biphenylen (PCB) mittels Gaschromatographie und massenspektrometrischer Detektion (GC-MS) oder Elektronen-Einfang-Detektion (GC-ECD)
Dieses Dokument legt Verfahren für die quantitative Bestimmung von sieben ausgewählten polychlorierten Biphenylen (PCB 28, PCB 52, PCB 101, PCB 118, PCB 138, PCB 153 und PCB 180) in Boden, Schlamm, Sediment, behandeltem Bioabfall und Abfall unter Anwendung der GC MS und GC ECD fest (siehe Tabelle 2).
[Tabelle 2]
Die Nachweisgrenze hängt von den zu bestimmenden Stoffen, den verwendeten Geräten, der Qualität der für die Extraktion der Probe verwendeten Chemikalien und der Reinigung des Extrakts ab.
Unter den in diesem Dokument festgelegten Bedingungen kann eine untere Anwendungsgrenze zwischen 1 μg/kg (angegeben als Trockenmasse) für Böden, Schlamm und Bioabfall und 10 μg/kg (angegeben als Trockenmasse) für Feststoffabfall erreicht werden. Bei einigen speziellen Proben kann die Grenze von 10 µg/kg nicht erreicht werden.
Schlamm, Abfall und behandelter Bioabfall können sich hinsichtlich ihrer Eigenschaften sowie hinsichtlich der erwarteten Kontaminationsniveaus von PCB und der Anwesenheit von störenden Stoffen unterscheiden. Aufgrund dieser Unterschiede ist es unmöglich, ein allgemeines Verfahren zu beschreiben. Dieses Dokument enthält Entscheidungstabellen, die auf den Eigenschaften der Probe und den anzuwendenden Extraktions- und Aufreinigungsverfahren basieren.
ANMERKUNG Für die Analyse von PCB in Isolierflüssigkeiten, Mineralölerzeugnissen, Gebrauchtölen und wässrigen Proben wird jeweils auf EN 61619, EN 12766 1 bzw. EN ISO 6468 verwiesen.
Das Verfahren kann für die Analyse weiterer, nicht im Anwendungsbereich festgelegter PCB Kongenere angewendet werden, vorausgesetzt, seine Eignung wurde durch geeignete laborinterne Validierungs¬untersuchungen nachgewiesen.
Matrices solides environnementales - Dosage des polychlorobiphényles (PCB) par chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) ou chromatographie en phase gazeuse avec détection par capture d’électrons (CG-ECD)
Le présent document spécifie les méthodes de dosage, par CG-SM et CG-ECD, de sept polychlorobiphényles choisis (PCB28, PCB52, PCB101, PCB118, PCB138, PCB153 et PCB180) dans les sols, les boues, les sédiments, les biodéchets traités et les déchets (voir Tableau 2).
La limite de détection dépend des composés à analyser, de l’équipement utilisé, de la qualité des réactifs chimiques utilisés pour l’extraction de l’échantillon et la purification de l’extrait.
Dans les conditions spécifiées dans le présent document, il est possible d’atteindre une limite inférieure d’application de 1 μg/kg (exprimée sur matière sèche) pour les sols, les boues et les biodéchets à 10 μg/kg (exprimée sur matière sèche) pour les déchets solides. Pour certains échantillons spécifiques, la limite de 10 μg/kg ne peut pas être atteinte.
Les boues, les déchets et les biodéchets traités peuvent présenter des différences en termes de propriétés, de niveaux prévus de contamination par les PCB et de présence de substances interférentes. En raison de ces différences, il est impossible de décrire un mode opératoire général. Le présent document contient des tables de décision basées sur les propriétés de l’échantillon ainsi que sur le mode opératoire d’extraction et de purification à utiliser.
NOTE Pour l’analyse des PCB dans les liquides isolants, les produits pétroliers, les huiles usagées et les échantillons aqueux, se référer respectivement aux normes EN 61619, EN 12766-1 et EN ISO 6468.
La méthode peut être appliquée à l’analyse de congénères de PCB autres que ceux décrits dans le domaine d’application, à condition d’en définir l’applicabilité par des tests de validation internes adaptés.
Trdni matriksi v okolju - Določanje polikloriranih bifenilov (PCB) s plinsko kromatografijo z masno selektivnim detektorjem (GC-MS) ali s plinsko kromatografijo z detektorjem z zajetjem elektronov (GC-ECD)
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SLOVENSKI STANDARD
SIST EN 17322:2020
01-november-2020
Nadomešča:
SIST EN 15308:2017
SIST EN 16167:2018+AC:2019
Trdni matriksi v okolju - Določanje polikloriranih bifenilov (PCB) s plinsko
kromatografijo z masno selektivnim detektorjem (GC-MS) ali s plinsko
kromatografijo z detektorjem z zajetjem elektronov (GC-ECD)
Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas
chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-
ECD)
Feststoffe in der Umwelt - Bestimmung von polychlorierten Biphenylen (PCB) mittels
Gaschromatographie und massenspektrometrischer Detektion (GC-MS) oder
Elektronen-Einfang-Detektion (GC-ECD)
Matrices solides environnementales - Dosage des polychlorobiphényles (PCB) par
chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) ou
chromatographie en phase gazeuse avec détection par capture d’électrons (CG-ECD)
Ta slovenski standard je istoveten z: EN 17322:2020
ICS:
13.030.10 Trdni odpadki Solid wastes
13.080.10 Kemijske značilnosti tal Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17322:2020 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
SIST EN 17322:2020
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SIST EN 17322:2020
EN 17322
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2020
EUROPÄISCHE NORM
ICS 13.030.01; 13.030.10; 13.030.20; 13.080.10 Supersedes EN 15308:2016, EN 16167:2018+AC:2019
English Version
Environmental Solid Matrices - Determination of
polychlorinated biphenyls (PCB) by gas chromatography -
mass selective detection (GC-MS) or electron-capture
detection (GC-ECD)
Matrices solides environnementales - Dosage des Feststoffe in der Umwelt - Bestimmung von
polychlorobiphényles (PCB) par chromatographie en polychlorierten Biphenylen (PCB) mittels
phase gazeuse-spectrométrie de masse (CG-SM) ou Gaschromatographie und massenspektrometrischer
chromatographie en phase gazeuse avec détection par Detektion (GC-MS) oder Elektronen-Einfang-Detektion
capture d'électrons (CG-ECD) (GC-ECD)
This European Standard was approved by CEN on 15 June 2020.
This European Standard was corrected and reissued by the CEN-CENELEC Management Centre on 9 September 2020.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATIO N
EUROPÄISCHES KOMITEE FÜR NORMUN G
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17322:2020 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST EN 17322:2020
EN 17322:2020 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Principle . 7
5 Interfer
...
SLOVENSKI STANDARD
SIST EN 17322:2020
01-november-2020
Nadomešča:
SIST EN 15308:2017
SIST EN 16167:2018+AC:2019
Trdni matriksi z vidika okolja - Določevanje polikloriranih bifenilov (PCB) s plinsko
kromatografijo z masno selektivnim detektorjem (GC-MS) ali s plinsko
kromatografijo z detektorjem z zajetjem elektronov (GC-ECD)
Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas
chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-
ECD)
Feststoffe in der Umwelt - Bestimmung von polychlorierten Biphenylen (PCB) mittels
Gaschromatographie und massenspektrometrischer Detektion (GC-MS) oder
Elektronen-Einfang-Detektion (GC-ECD)
Matrices solides environnementales - Dosage des polychlorobiphényles (PCB) par
chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) ou
chromatographie en phase gazeuse avec détection par capture d’électrons (CG-ECD)
Ta slovenski standard je istoveten z: EN 17322:2020
ICS:
13.030.10 Trdni odpadki Solid wastes
13.080.10 Kemijske značilnosti tal Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17322:2020 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
SIST EN 17322:2020
---------------------- Page: 2 ----------------------
SIST EN 17322:2020
EN 17322
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2020
EUROPÄISCHE NORM
ICS 13.030.01; 13.030.10; 13.030.20; 13.080.10 Supersedes EN 15308:2016, EN 16167:2018+AC:2019
English Version
Environmental Solid Matrices - Determination of
polychlorinated biphenyls (PCB) by gas chromatography -
mass selective detection (GC-MS) or electron-capture
detection (GC-ECD)
Matrices solides environnementales - Dosage des Feststoffe in der Umwelt - Bestimmung von
polychlorobiphényles (PCB) par chromatographie en polychlorierten Biphenylen (PCB) mittels
phase gazeuse-spectrométrie de masse (CG-SM) ou Gaschromatographie und massenspektrometrischer
chromatographie en phase gazeuse avec détection par Detektion (GC-MS) oder Elektronen-Einfang-Detektion
capture d'électrons (CG-ECD) (GC-ECD)
This European Standard was approved by CEN on 15 June 2020.
This European Standard was corrected and reissued by the CEN-CENELEC Management Centre on 9 September 2020.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATIO N
EUROPÄISCHES KOMITEE FÜR NORMUN G
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17322:2020 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST EN 17322:2020
EN 17322:2020 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Principle . 7
5
...
SLOVENSKI STANDARD
SIST EN 17322:2020
01-november-2020
Nadomešča:
SIST EN 15308:2017
SIST EN 16167:2018+AC:2019
Trdni matriksi z vidika okolja - Določevanje polikloriranih bifenilov (PCB) s plinsko
kromatografijo z masno selektivnim detektorjem (GC-MS) ali s plinsko
kromatografijo z detektorjem z zajetjem elektronov (GC-ECD)
Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas
chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-
ECD)
Feststoffe in der Umwelt - Bestimmung von polychlorierten Biphenylen (PCB) mittels
Gaschromatographie und massenspektrometrischer Detektion (GC-MS) oder
Elektronen-Einfang-Detektion (GC-ECD)
Matrices solides environnementales - Dosage des polychlorobiphényles (PCB) par
chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) ou
chromatographie en phase gazeuse avec détection par capture d’électrons (CG-ECD)
Ta slovenski standard je istoveten z: EN 17322:2020
ICS:
13.030.10 Trdni odpadki Solid wastes
13.080.10 Kemijske značilnosti tal Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
SIST EN 17322:2020 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
SIST EN 17322:2020
---------------------- Page: 2 ----------------------
SIST EN 17322:2020
EN 17322
EUROPEAN STANDARD
NORME EUROPÉENNE
July 2020
EUROPÄISCHE NORM
ICS 13.030.01; 13.030.10; 13.030.20; 13.080.10 Supersedes EN 15308:2016, EN 16167:2018+AC:2019
English Version
Environmental Solid Matrices - Determination of
polychlorinated biphenyls (PCB) by gas chromatography -
mass selective detection (GC-MS) or electron-capture
detection (GC-ECD)
Matrices solides environnementales - Dosage des Feststoffe in der Umwelt - Bestimmung von
polychlorobiphényles (PCB) par chromatographie en polychlorierten Biphenylen (PCB) mittels
phase gazeuse-spectrométrie de masse (CG-SM) ou Gaschromatographie und massenspektrometrischer
chromatographie en phase gazeuse avec détection par Detektion (GC-MS) oder Elektronen-Einfang-Detektion
capture d'électrons (CG-ECD) (GC-ECD)
This European Standard was approved by CEN on 15 June 2020.
This European Standard was corrected and reissued by the CEN-CENELEC Management Centre on 9 September 2020.
CEN members are bound to comply with the CEN/CENELEC Internal Regulations which stipulate the conditions for giving this
European Standard the status of a national standard without any alteration. Up-to-date lists and bibliographical references
concerning such national standards may be obtained on application to the CEN-CENELEC Management Centre or to any CEN
member.
This European Standard exists in three official versions (English, French, German). A version in any other language made by
translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC Management
Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania, Luxembourg, Malta, Netherlands, Norway,
Poland, Portugal, Republic of North Macedonia, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland, Turkey and
United Kingdom.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATIO N
EUROPÄISCHES KOMITEE FÜR NORMUN G
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2020 CEN All rights of exploitation in any form and by any means reserved Ref. No. EN 17322:2020 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
SIST EN 17322:2020
EN 17322:2020 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions . 6
4 Principle . 7
5
...
SLOVENSKI STANDARD
oSIST prEN 17322:2018
01-november-2018
7UGQLPDWULNVL]YLGLNDRNROMD'RORþHYDQMHSROLNORULUDQLKELIHQLORY 3&% VSOLQVNR
NURPDWRJUDILMR]PDVQRVHOHNWLYQLPGHWHNWRUMHP *&06 DOLVSOLQVNR
NURPDWRJUDILMR]GHWHNWRUMHP]]DMHWMHPHOHNWURQRY *&(&'
Environmental Solid Matrices - Determination of polychlorinated biphenyls (PCB) by gas
chromatography - mass selective detection (GC-MS) or electron-capture detection (GC-
ECD)
Schlamm, behandelter Bioabfall, Abfällen und Boden - Bestimmung von polychlorierten
Biphenylen (PCB) mittels Gaschromatographie mit Massenspektrometrie-Kopplung (GC-
MS) und Gaschromatographie mit Elektroneneinfangdetektion (GC-ECD)
Matrices solides environnementales - Détermination des biphényles polychlorés (PCB)
par chromatographie en phase gazeuse-spectrométrie de masse (CG-SM) ou
chromatographie en phase gazeuse avec détection par capture d'électrons (CG-DCE)
Ta slovenski standard je istoveten z: prEN 17322
ICS:
13.030.10 Trdni odpadki Solid wastes
13.080.10 .HPLMVNH]QDþLOQRVWLWDO Chemical characteristics of
soils
71.040.50 Fizikalnokemijske analitske Physicochemical methods of
metode analysis
oSIST prEN 17322:2018 en,fr,de
2003-01.Slovenski inštitut za standardizacijo. Razmnoževanje celote ali delov tega standarda ni dovoljeno.
---------------------- Page: 1 ----------------------
oSIST prEN 17322:2018
---------------------- Page: 2 ----------------------
oSIST prEN 17322:2018
DRAFT
EUROPEAN STANDARD
prEN 17322
NORME EUROPÉENNE
EUROPÄISCHE NORM
November 2018
ICS 13.030.10; 13.030.20; 13.080.10 Will supersede EN 15308:2016, EN 16167:2018
English Version
Environmental Solid Matrices - Determination of
polychlorinated biphenyls (PCB) by gas chromatography -
mass selective detection (GC-MS) or electron-capture
detection (GC-ECD)
Matrices solides environnementales - Détermination Schlamm, behandelter Bioabfall, Abfällen und Boden -
des biphényles polychlorés (PCB) par chromatographie Bestimmung von polychlorierten Biphenylen (PCB)
en phase gazeuse-spectrométrie de masse (CG-SM) ou mittels Gaschromatographie mit
chromatographie en phase gazeuse avec détection par Massenspektrometrie-Kopplung (GC-MS) und
capture d'électrons (CG-DCE) Gaschromatographie mit Elektroneneinfangdetektion
(GC-ECD)
This draft European Standard is submitted to CEN members for enquiry. It has been drawn up by the Technical Committee
CEN/TC 444.
If this draft becomes a European Standard, CEN members are bound to comply with the CEN/CENELEC Internal Regulations
which stipulate the conditions for giving this European Standard the status of a national standard without any alteration.
This draft European Standard was established by CEN in three official versions (English, French, German). A version in any other
language made by translation under the responsibility of a CEN member into its own language and notified to the CEN-CENELEC
Management Centre has the same status as the official versions.
CEN members are the national standards bodies of Austria, Belgium, Bulgaria, Croatia, Cyprus, Czech Republic, Denmark, Estonia,
Finland, Former Yugoslav Republic of Macedonia, France, Germany, Greece, Hungary, Iceland, Ireland, Italy, Latvia, Lithuania,
Luxembourg, Malta, Netherlands, Norway, Poland, Portugal, Romania, Serbia, Slovakia, Slovenia, Spain, Sweden, Switzerland,
Turkey and United Kingdom.
Recipients of this draft are invited to submit, with their comments, notification of any relevant patent rights of which they are
aware and to provide supporting documentation.
Warning : This document is not a European Standard. It is distributed for review and comments. It is subject to change without
notice and shall not be referred to as a European Standard.
EUROPEAN COMMITTEE FOR STANDARDIZATION
COMITÉ EUROPÉEN DE NORMALISATION
EUROPÄISCHES KOMITEE FÜR NORMUNG
CEN-CENELEC Management Centre: Rue de la Science 23, B-1040 Brussels
© 2018 CEN All rights of exploitation in any form and by any means reserved Ref. No. prEN 17322:2018 E
worldwide for CEN national Members.
---------------------- Page: 3 ----------------------
oSIST prEN 17322:2018
prEN 17322:2018 (E)
Contents Page
European foreword . 3
Introduction . 4
1 Scope . 5
2 Normative references . 5
3 Terms and definitions .
...
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